Aim :
To study the effect of temperature on the rate of reaction.
Problem statement : How does the temperature of sodium thiosulphate, Na2S2O3, solution
affect the rate of reaction?
Hypothesis : The rate of reaction will increase if the temperature
of sodium thiosulphate, Na2S2O3, solution increases.
Variables :-
Manipulated variable : Temperature of sodium thiosulphate, Na2S2O3,
solution. (reaction)
Responding
variable : Rate of reaction.
Controlled variables : Volume and concentration of sulphuric acid,
H2SO4, volume and concentration of sodium thiosulphate, Na2S2O3, solution.
Operational definition : The time taken for the mark “X” to disappear
from sight in different temperature when the sodium thiosulphate, Na2S2O3,
solution react with sulphuric acid, H2SO4
The rate of reaction is measured by how fast the
'X' is hidden by the yellow precipitate.
Apparatus : 50cm3 measuring cylinder, 100cm3 conical flask,
10cm3 measuring cylinder, stopwatch, thermometer, Bunsen burner, wire gauze,
tripod stand
Materials : 0.2 mol dm-3 sodium thiosulphate, Na2S2O3,
solution, 0.1mol dm-3 sulphuric acid, H2SO4, white paper marked “X” at the
centre
Procedure :-
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1.
An “X” is marked using a pencil on the
centre of a piece of white paper.
2.
50cm3 of 0.2 mol dm-3 sodium
thiosulphate, Na2S2O3, solution is measured with a 50cm3 measuring cylinder and
is poured into a conical flask.
.
3.
Using a 10cm3 measuring cylinder, 5cm3
of 0.1mol dm-3 sulphuric acid, H2SO4 is measured.
4.
The sodium thiosulphate, Na2S2O3,
solution is heated with a Bunsen burner and quickly placed on the “X” mark on
the piece of white paper when it reaches 30c.
5.
Sulphuric acid, H2SO4 is immediately and
carefully poured into the conical flask containing 50cm3 of 30c of sodium
thiosulphate, Na2S2O3, solution. At the same time, the stopwatch is started.
6.
The conical flask is shaken slowly
throughout the experiment on the white paper.
7.
The mark “X” is observed vertically from
the top part of the conical flask through the solution.
8.
The stopwatch is stopped quickly as the
mark “X” on the white paper is no longer visible.
9.
The time taken, for the mark “X” to disappear
from sight is recorded.
10. Steps
1 to 9 are repeated four more times using different temperature of 0.2 mol dm-3
sodium thiosulphate, Na2S2O3, solution at 35c, 40c, 45c and 50c. Whereas the
other conditions remain unchanged.
11. The
results are recorded in a table.
Data and observations :-
Temperature of
sodium thiosulphate, Na2S2O3, solution/ c
|
30
|
35
|
40
|
45
|
50
|
Time/ s
|
9.8
|
8.7
|
8
|
6
|
5.2
|
1/time/ s-1
|
|
|
|
|
|
Interpreting data :-
1.
Based on the results, two graphs are
plotted.
(a)
The graph of the temperature of sodium thiosulphate,
Na2S2O3, solution against the time taken for the mark “X” to disappear from
sight.
(b)
The graph of the temperature of sodium
thiosulphate, Na2S2O3, solution against 1/time.
2.
Based on the graph plotted, determine
the relationships between the temperature of sodium thiosulphate, Na2S2O3,
solution with
(a)
The time taken
-
As the temperature of sodium
thiosulphate, Na2S203, solution decreases, a longer time is needed for mark ‘X’
to disappear from sight. Therefore, as
the temperature becomes lower, the rate of reaction also decreases.
(b)
1/time
-
The temperature rises, the value of
1/time or rate of reaction also increases.
3.
Deduce the effect of the temperature a
reactant on the rate of reaction.
-
The relationship between the rate of
reaction and the temperature of sodium thiosulphate, Na2S2O3, solution is, when
the temperature of a reactant increases, the rate of reaction increases.
Discussion :-
1.
Write down the chemical equation for the
reaction between sodium thiosulphate, Na2S2O3, solution and dilute sulphuric
acid, H2SO4.
-
S2O3(aq) + 2H(aq) → S(s) + SO2(g) + H2O(l)
2.
Name the yellow precipitate which is formed
throughout the experiment?
-
The yellow precipitate formed is sulphur.
3.
Why are the volume and concentration of both the
sodium thiosulphate, Na2S2O3, solution and sulphuric acid, H2SO4 used remain
constant for each set of the experiment?
-
Conclusion : Hypothesis is accepted. The rate of reaction will
increase if the temperature of sodium thiosulphate, Na2S2O3, solution
increases.